Gold plating can be done on most metals such as nickel brass stainless steel silver and copper.
Gold plated copper.
A gold plated silver article is usually a silver substrate with layers of copper nickel and gold deposited on top of it.
Silver and gold tend to diffuse into each other which can cause a plated piece to become dull or tarnished looking as the gold plating wears.
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Most gold plated jewelry is made with a silver base but other metals such as copper or aluminum can be gold plated as well.
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Gold plated tungsten ring.
Modern industrial metals such as tungsten and titanium are also frequently gold plated.
Of these silver and copper are the most commonly used.
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For example a ring in which the base metal is copper or silver but that has a thin layer of gold on the outer surface would be considered a gold plated item of jewelry.
Copper is usually plated with nickel before being plated with gold and gold can be plated to almost any thickness from only a few micro inches up to whatever thickness you are likely to want.
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Gold can be plated directly over copper but the copper will migrate into the gold layer over time.